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1.2.2 Decomposition Reaction


                                                                  Activity 1.5
                                                                  Activity 1.5
                                                                  Activity
                                                                              1.5
                                                                  Activity 1.51.5
                                                                  Activity
                                                                n Take about 2 g ferrous sulphate crystals
                                                                   in a dry boiling tube.
                                                                n Note the colour of the ferrous sulphate
                                                                   crystals.
                                                                n Heat the boiling tube over the  flame  of
                                                                   a burner or spirit lamp as shown in
                                                                   Fig. 1.4.
                                                                n Observe the colour of the crystals after
                                                                   heating.


              Figure 1.4                Have you noticed that the green colour of the ferrous sulphate crystals
              Correct way of heating
              the boiling tube       has changed? You can also smell the characteristic odour of burning
              containing crystals    sulphur.
              of ferrous sulphate
                                                      Heat
              and of smelling the       2FeSO (s)         Fe O (s)  +  SO (g)  + SO (g)           (1.19)
                                                           →
                                               4                2  3        2        3
              odour
                                        (Ferrous sulphate)    (Ferric oxide)
                                        In this reaction you can observe that a single reactant breaks down
                                     to give simpler products. This is a decomposition reaction. Ferrous
                                     sulphate crystals (FeSO . 7H O) lose water when heated and the colour
                                                             4    2
                                     of the crystals changes. It then decomposes to ferric oxide (Fe O ),
                                                                                                       2  3
                                     sulphur dioxide (SO ) and sulphur trioxide (SO ). Ferric oxide is a solid,
                                                         2                         3
                                     while SO  and SO  are gases.
                                              2        3
                                        Decomposition of calcium carbonate to calcium oxide and carbon
                                     dioxide on heating is an important decomposition reaction used in
                                     various industries. Calcium oxide is called lime or quick lime. It has
                                     many uses – one is in the manufacture of cement. When a decomposition
                                     reaction is carried out by heating, it is called thermal decomposition.
                                                     Heat
                                        CaCO (s)         CaO(s)    +   CO (g)                     (1.20)
                                                          →
                                              3                             2
                                        (Limestone)           (Quick lime)
                                                 Another example of a thermal decomposition reaction is given
                                                 in Activity 1.6.

                                                                   Activity
                                                                   Activity    1.6
                                                                   Activity 1.6
                                                                   Activity 1.61.6
                                                                   Activity 1.6
                                                            n Take about 2 g lead nitrate powder in a boiling
                                                              tube.
                                                            n Hold the boiling tube with a pair of tongs and
                                                              heat it over a flame, as shown in Fig. 1.5.
                                                            n What do you observe? Note down the change,
                                                              if any.

                                                             You will observe the emission of brown fumes.
              Figure 1.5
              Heating of lead nitrate and                These fumes are of nitrogen dioxide (NO ). The
                                                                                                     2
              emission of nitrogen dioxide               reaction that takes place is –


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