Page 44 - Understanding NCERT Science 09
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The rules that you have to follow while writing   3. Formula of carbon tetrachloride
                 a chemical formula are as follows:
                 •   the valencies or charges on the ion
                     must balance.
                 •   when a compound consists of a metal and
                     a non-metal, the name or symbol of the
                     metal is written first. For example: calcium
                     oxide (CaO), sodium chloride (NaCl), iron
                     sulphide (FeS), copper oxide (CuO), etc.,
                     where oxygen, chlorine, sulphur are non-        For magnesium chloride, we write the
                     metals   and are written on the right,      symbol of cation (Mg ) first followed by the
                                                                                       2+
                     whereas calcium, sodium, iron and           symbol of anion (Cl ). Then their charges are
                                                                                     -
                     copper are metals, and are written on       criss-crossed to get the formula.
                     the left.
                 •   in compounds formed with polyatomic ions,     4.    Formula of magnesium chloride
                     the number of ions present in the
                     compound is indicated by enclosing the
                     formula of ion in a bracket and writing the
                     number of ions outside the bracket. For
                     example, Mg (OH) . In case the number of
                                       2
                     polyatomic ion is one, the bracket is not                  Formula : MgCl  2
                     required. For example, NaOH.
                                                                     Thus, in magnesium chloride, there are
                 3.4.1 FORMULAE OF SIMPLE COMPOUNDS                                    -
                                                                 two chloride ions (Cl ) for each magnesium
                 The simplest compounds, which are made up       ion (Mg ). The positive and negative charges
                                                                         2+

                 of two different elements are called binary     must balance each other and the overall
                 compounds. Valencies of some ions are given     structure must be neutral. Note that in the
                 in Table 3.6. You can use these to write
                 formulae for compounds.                         formula, the charges on the ions are
                                                                 not indicated.
                    While writing the chemical formulae for
                 compounds, we write the constituent elements
                 and their valencies as shown below. Then we     Some more examples
                 must crossover the valencies of the               (a)   Formula for aluminium oxide:
                 combining atoms.


                 Examples
                  1. Formula of hydrogen chloride
                                                                                Formula : Al O
                                                                                             2  3


                                                                   (b)   Formula for calcium oxide:
                  Formula of the compound would be HCl.

                  2. Formula of hydrogen sulphide


                                                                     Here, the valencies of the two elements
                                                                 are the same. You may arrive at the formula
                                                                 Ca O . But we simplify the formula as CaO.
                                                                    2  2

                 ATOMS AND MOLECULES                                                                     33





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