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we use the word formula unit for those                uestions
                 substances whose constituent particles are
                 ions. For example, sodium chloride as                   1. Calculate the molecular masses
                 discussed above, has a formula unit NaCl. Its               of H , O , Cl , CO , CH , C H ,
                                                                                          2
                                                                                                         2
                                                                                 2
                                                                                     2
                                                                                                            6
                                                                                                2
                                                                                                     4
                 formula unit mass can be calculated as–         Q           C H , NH ,  CH OH.
                                                                              2
                                                                                 4
                                                                                      3
                                                                                            3
                          1 × 23 + 1 × 35.5 = 58.5 u                     2. Calculate the formula unit
                                                                                               2
                                                                                                     2
                                                                                                         3
                  Example 3.2 Calculate the formula unit                     masses of ZnO, Na O, K CO ,
                                                                             given atomic masses of Zn = 65 u,
                     mass of CaCl .
                                   2                                         Na = 23 u, K = 39 u, C = 12 u,
                  Solution:                                                  and O = 16 u.
                         Atomic mass of Ca
                         + (2 × atomic mass of Cl)
                         = 40 + 2 × 35.5 = 40 + 71 = 111 u
                                       What
                                       you have
                                       learnt
                                       •     During a chemical reaction, the sum of the masses of the
                                             reactants and  products remains unchanged. This is known
                                             as the Law of Conservation of Mass.
                                       •     In a pure chemical compound, elements are always present
                                             in a definite proportion by mass. This is known as the Law
                                             of Definite Proportions.
                                       •     An atom is the smallest particle of the element that cannot
                                             usually exist independently and retain all its chemical
                                             properties.
                                       •     A molecule is the smallest particle of an element or a
                                             compound capable of independent existence under ordinary
                                             conditions. It shows all the properties of the substance.
                                       •     A chemical formula of a compound shows its constituent
                                             elements and the number of atoms of each combining
                                             element.
                                       •     Clusters of atoms that act as an ion are called polyatomic
                                             ions.  They carry a fixed charge on them.
                                       •     The chemical formula of a molecular compound is
                                             determined by the valency of each element.
                                       •     In ionic compounds, the charge on each ion is used to
                                             determine the chemical formula of the compound.








                 ATOMS AND MOLECULES                                                                     35





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