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points of these compounds. Since the electrons are shared between
                 atoms and no charged particles are formed, such covalent compounds
                 are generally poor conductors of electricity.



                                           Allotropes of carbon
                       The element carbon occurs in different forms in nature with
                       widely varying physical properties. Both diamond and
                       graphite are formed by carbon atoms, the difference lies in
                       the manner in which the carbon atoms are bonded to one
                                                                                         Figure 4.5
                                                                                         Figure 4.5
                                                                                         Figure 4.5
                                                                                         Figure 4.5
                                                                                         Figure 4.5
                       another. In diamond, each carbon atom is bonded to four
                                                                                         Electron dot structure for
                       other carbon atoms forming a rigid three-dimensional              methane
                       structure. In graphite, each carbon atom is bonded to three
                       other carbon atoms in the same plane giving a hexagonal array.
                       One of these bonds is a double-bond, and thus the valency of
                       carbon is satisfied. Graphite structure is formed by the
                       hexagonal arrays being placed in layers one above the other.
                   More to Know!









                        The structure of diamond
                                                                                         The structure of C-60
                                                         The structure of graphite
                                                                                         Buckminsterfullerene
                       These two different structures result in diamond and graphite having very different
                       physical properties even though their chemical properties are the same. Diamond is
                       the hardest substance known while graphite is smooth and slippery. Graphite is also
                       a very good conductor of electricity unlike other non-metals that you studied in the
                       previous Chapter.
                       Diamonds can be synthesised by subjecting pure carbon to very high pressure and
                       temperature. These synthetic diamonds are small but are otherwise indistinguishable
                       from natural diamonds.
                       Fullerenes form another class of carbon allotropes. The first one to be identified was
                       C-60 which has carbon atoms arranged in the shape of a football. Since this looked
                       like the geodesic dome designed by the US architect Buckminster Fuller, the molecule
                       was named fullerene.



                                     Q      U       E     S     T      I     O      N      S


                    1.    What would be the electron dot structure of carbon dioxide which has
                          the formula CO ?
                                        2
                    2.    What would be the electron dot structure of a molecule of sulphur which  ?
                          is made up of eight atoms of sulphur? (Hint – The eight atoms of sulphur
                          are joined together in the form of a ring.)



                 Carbon and its Compounds                                                                  61


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