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But, let us take another look at butane. If we make the carbon
                 ‘skeleton’ with four carbon atoms, we see that two different possible
                 ‘skeletons’ are –

                    C—C—C—C

                                 Figure 4.8
                                 Figure 4.8
                                 Figure 4.8 (a) Two possible carbon-skeletons
                                 Figure 4.8
                                 Figure 4.8
                    Filling the remaining valencies with hydrogen gives us –





                     Figure 4.8
                     Figure 4.8
                     Figure 4.8 (b) Complete molecules for two structures with formula C H
                     Figure 4.8
                     Figure 4.8
                                                                                4  10
                    We see that both these structures have the same formula C H . Such
                                                                             4  10
                 compounds with identical molecular formula but different structures
                 are called structural isomers.
                    In addition to straight and branched carbon chains, some compounds
                 have carbon atoms arranged in the form of a ring. For example, cyclohexane
                 has the formula C H  and the following structure –
                                   6  12







                         (a)                                 (b)
                 Figure 4.9 Structure of cyclohexane (a) carbon skeleton (b) complete molecule
                 Figure 4.9
                 Figure 4.9
                 Figure 4.9
                 Figure 4.9
                    Can you draw the electron dot structure for cyclohexane? Straight
                 chain, branched chain and cyclic carbon compounds, all may be saturated
                 or unsaturated. For example, benzene, C H , has the following structure –
                                                        6  6



                                      Benzene — C H
                                                   6  6


                                      Figure 4.10 Structure of benzene
                                      Figure 4.10
                                      Figure 4.10
                                      Figure 4.10
                                      Figure 4.10
                    All these carbon compounds which contain only carbon and
                 hydrogen are called hydrocarbons. Among these, the saturated
                 hydrocarbons are called alkanes. The unsaturated hydrocarbons which
                 contain one or more double bonds are called alkenes. Those containing
                 one or more triple bonds are called alkynes.
                 4.2.3 Will you be my Friend?

                 Carbon seems to be a very friendly element. So far we have been looking at
                 compounds containing carbon and hydrogen only. But carbon also forms


                 Carbon and its Compounds                                                                  65


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