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4.    Draw the structures for the following compounds.
                                                                                               ?
                           (i) Ethanoic acid               (ii)     Bromopentane*
                          (iii) Butanone                   (iv)     Hexanal.
                          *Are structural isomers possible for bromopentane?
                    5.    How would you name the following compounds?


                           (i) CH —CH —Br                  (ii)
                                  3    2



                          (iii)



                 4.3 CHEMICAL PROPERTIES OF CARBON COMPOUNDS

                 In this section we will be studying about some of the chemical properties
                 of carbon compounds. Since most of the fuels we use are either carbon
                 or its compounds, we shall first study combustion.

                4.3.1 CombustionCombustion
                4.3.1
                 4.3.1
                         Combustion
                 4.3.1 Combustion
                 4.3.1 Combustion
                 Carbon, in all its allotropic forms, burns in oxygen to give carbon dioxide
                 along with the release of heat and light. Most carbon compounds also
                 release a large amount of heat and light on burning. These are the
                 oxidation reactions that you learnt about in the first Chapter –
                    (i) C + O  → CO  + heat and light
                             2      2
                   (ii) CH  + O  → CO  + H O + heat and light
                           4    2      2    2
                   (iii) CH CH OH + O  → CO  + H O + heat and light
                           3   2       2      2    2
                    Balance the latter two reactions like you learnt in the first Chapter.
                                                                                Activity
                      Activity 4.34.3
                      Activity 4.3
                                                                                            4.4
                                                                                Activity
                                                                                Activity 4.4
                                                                                Activity 4.4
                      Activity 4.3                                              Activity 4.44.4
                                  4.3
                      Activity
                      Activity
                  CAUTION: This Activity needs the teacher’s assistance.      n Light a bunsen burner and
                  n Take some carbon compounds (naphthalene,                    adjust the air hole at the
                    camphor, alcohol) one by one on a spatula and burn          base to get different types of
                    them.                                                       flames/presence of smoke.
                  n Observe the nature of the flame and note whether          n When do you get a yellow,
                    smoke is produced.                                          sooty flame?
                                                                              n When do you get a blue
                  n Place a metal plate above the flame. Is there a deposition  flame?
                    on the plate in case of any of the compounds?
                    Saturated hydrocarbons will generally give a clean flame while
                 unsaturated carbon compounds will give a yellow flame with lots of
                 black smoke. This results in a sooty deposit on the metal plate in Activity
                 4.3. However, limiting the supply of air results in incomplete combustion
                 of even saturated hydrocarbons giving a sooty flame. The gas/kerosene
                 stove used at home has inlets for air so that a sufficiently oxygen-rich


                 Carbon and its Compounds                                                                  69


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